Chemistry

Ideal Gas Law (PV = nRT): Steps, Units and Examples

Solve gas problems with PV = nRT: pick R, convert to kelvin, and watch your units, with two worked chemistry examples.

The equation

P in atm, V in liters, n in moles, T in kelvin.

Before you plug in

Temperature must be in kelvin every time.

Example 1

0.50 mol of gas is in a 10. L container at 300 K. Find the pressure.

  1. P = nRT / V
  2. = (0.50)(0.0821)(300) / 10.
P ≈ 1.2 atm

Example 2

What volume does 1.0 mol of gas occupy at 1.0 atm and 273 K?

  1. V = nRT / P
  2. = (1.0)(0.0821)(273) / 1.0
V ≈ 22 L

Common mistake

T = 27 (in °C)

Always convert to kelvin: 27 °C = 300 K.

If pressure is in kPa or mmHg, convert it or use the matching R.

Volume must be in liters with R = 0.0821.

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